A new criterion to identify safe operating conditions for isoperibolic homogeneous semi-batch reactions
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- 作者：Wenshuai Bai ; Lin Hao ; Zichao Guo ; Yangyang Liu ; Rui Wang ; Hongyuan Wei ; crystallization.wei@hotmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Semi-batch reactor ; Isoperibolic reaction ; Runaway criterion ; MTSR ; Inherently safe
- 刊名：Chemical Engineering Journal
- 出版年：2017
- 出版时间：15 January 2017
- 年：2017
- 卷：308
- 期：Complete
- 页码：8-17
- 全文大小：1182 K
文摘
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A new runaway criterion to distinguish different reactor behaviors (IS, MI, TR and QFS) is proposed.
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The chemical process may be in a potential runaway situation if θMTSR < 1.
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A robust procedure to identify generalized inherently safe (GIS) operating conditions for isoperibolic homogeneous SBRs is proposed with limited kinetic information.
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The determined GIS operating conditions involve the information of both a sufficiently low accumulation and MTSR lower than MAT.
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