pH influences on Pb2+ removal by the biopolymer in activated sludge were disclosed.
Total removal rate of Pb2+ increased with rising system pH value.
Biosorption was predominant for Pb2+ removal under acid conditions.
Biosorption and Pb(OH)2 precipitation co-existed under alkaline conditions.
Pb(OH)2 excelled biosorption in capturing Pb2+ under alkaline conditions.
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