Direct amination of dodecanol with NH3 over heterogeneous catalysts. Catalyst screening and kinetic modelling
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- 作者：Doris Ruiza ; b ; Atte Ahoa ; Tiina Salorantac ; Kari Erä ; nena ; Johan Wä ; rnå ; a ; Reko Leinoc ; Dmitry Yu. Murzina ; dmurzin@abo.fi" class="auth_mail" title="E-mail the corresponding author
- 关键词：Amination ; Fatty alcohols ; Fatty amines ; Ammonia ; Heterogeneous catalysts
- 刊名：Chemical Engineering Journal
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：307
- 期：Complete
- 页码：739-749
- 全文大小：1149 K
文摘
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Direct amination of dodecanol to dodecylamine over heterogeneous catalysts.
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High selectivity and yield of dodecylamine.
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Rate independence on ammonia pressure.
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Unusual hydrogen pressure dependence for dehydrogenation reactions.
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Mechanistic kinetic model adequately described experimental data.
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