One-step synthesis of N-doped activated carbon with controllable Ni nanorods for ethanol oxidation

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• 作者：Wenjuan Shi^a ; Haiyan Gao^a ; Jianguo Yu^b ; ^{hh_y1118@hotmail.com" class="auth_mail" title="E-mail the corresponding author} ; Miaomiao Jia^b ; Tangming Dai^b ; Yongnan Zhao^a ; ^{zhaoyn@263.net" class="auth_mail" title="E-mail the corresponding author} ; Jingjing Xu^b ; Guodong Li^c
• 关键词：Nickel nanorods ; Nitrogen-doping ; Activated carbon ; Ethanol oxidation
• 刊名：Electrochimica Acta
• 出版年：2016
• 出版时间：1 December 2016
• 年：2016
• 卷：220
• 期：Complete
• 页码：486-492
• 全文大小：2482 K

文摘

N-doped activated carbons with controllable Ni nanorods (NiNC) catalysts were fabricated by a facile one-pot method for electrocatalytic oxidation of ethanol. The effects of carbon source and Ni precursor for the different microstructures of the forming Ni are discussed in this work. The sucrose and chloride ion are the key factors for forming nanorod-like nickel catalyst. The sizes of Ni nanorods can be controlled by the reactant ratios and influence the catalytic performance for ethanol oxidation. The doped N atoms are also used to improve the catalytic performance for ethanol oxidation. The NiNC–3 catalyst with the proper content and size of Ni exhibits an improved catalytic activity toward ethanol oxidation with a 5 times current density and 16 times rate constant in comparison with the NiNC–1 catalysts. A current density of 47.5 mA cm⁻² is generated on NiNC–3 electrode. Furthermore, current density retention of 80.7% suggests an excellent cyclic stability after 1500 cycle on the NiNC–3 electrode. All of these elevated performances can be attributed to the relatively uniform nanorods size, as well as the excellent electrical conductivity and stability of the carbon support.