Three unique MOFs constructed by 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene and dicarboxylates: From rhombic tetrameric zinc(II) 2D layer to 2D + 2D → 3D polycatenated frameworks
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- 作者：Jie Zhou ; Tong Yan ; Yong-Feng Qiao ; Yi-Dan Zhao ; Xiao Wang ; Lin Du ; Ming-Jin Xie ; Jian Xu ; Qi-Hua Zhao ; qhzhao@ynu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Bis-pyridyl ligand ; Coordination polymer ; Crystal structure ; Magnetic property ; Polycatenated framework
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：73
- 期：Complete
- 页码：161-165
- 全文大小：980 K
文摘
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Complex 1 has a unique 2D double-layered framework containing rhombic tetrameric Zn(II) of mixed Td and Oh geometries.
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10">Complex 2 shows a 2D + 2D → 3D parallel polycatenated framework with cuboids as the fundamental building units.
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15">Complex 3 possess an interesting 2D → 3D inclined polycatenation net based on 44-sql subunits.
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The photoluminescent properties of 1 and 2, and magnetic properties of 3 were studied.
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