Calculation of the franck-condon factors for the transitions of CS⁺₂ ions and comparison with related photodissociation spectra

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• 作者：Yuchao Ma ; Limin Zhang ; Xiujuan Zhuang ; Jinting Wang ; Maoping Yang ; Shuqin Yu
• 关键词：CS⁺₂ ions ; Franck-Condon factors ; Photodissociation spectra
• 刊名：Acta Physico-Chimica Sinica
• 出版年：2006
• 出版时间：December 2006
• 年：2006
• 卷：22
• 期：12
• 页码：1532-1535
• 全文大小：339 K

文摘

On the basis of the approximation of harmonic oscillation between SC and S for the symmetric stretching vibration of the CS₂⁺ ions, the Franck-Condon factors for the transitions of CS⁺₂ ions have been calculated using the potential curves and wavefunctions of the harmonic oscillator. The calculation results have been used for comparison with the photodissociation spectra via the transition, and for estimating the validity of the rotation constants and the bond length of state given in the previous studies. The photodissociation mechanism via the transitions of CS⁺₂ ions has also been discussed.