Synthesis and characterization of niobium-promoted cobalt/iron catalysts supported on carbon nanotubes for the hydrogenation of carbon monoxide

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• 作者：Zahra Gholami^a ; ^{zahra.gholami@petronas.com.my" class="auth_mail" title="E-mail the corresponding author} ; Noor Asmawati Mohd Zabidi^b ; Fatemeh Gholami^c ; Mohammadtaghi Vakili^d
• 关键词：Fischer-Tropsch synthesis ; bimetallic catalyst ; niobium promoter ; carbon nanotubes
• 刊名：Journal of Fuel Chemistry and Technology
• 出版年：2016
• 出版时间：July 2016
• 年：2016
• 卷：44
• 期：7
• 页码：815-821
• 全文大小：3991 K

文摘

Bimetallic Co/Fe catalysts supported on carbon nanotubes (CNTs) were prepared, and niobium (Nb) was added as promoter to the 70Co:30Fe/CNT catalyst. The physicochemical properties of the catalysts were characterized, and the catalytic performances were analyzed at the same operation conditions (H₂:CO (volume ratio) = 2:1, p = 1 MPa, and t = 260°C) in a tubular fixed-bed microreactor system. The addition of Nb to the bimetallic catalyst decreases the average size of the oxide nanoparticles and improves the reducibility of the bimetallic catalyst. Evaluation of the catalyst performance in a Fischer-Tropsch reaction shows that the catalyst results in high selectivity to methane, and the selectivity to C₅₊ increased slightly in the bimetallic catalyst unlike that in the monometallic catalysts. The addition of 1% Nb to the bimetallic catalyst increases CO conversion and selectivity to C₅₊. Meanwhile, a decrease in methane selectivity is observed.