α-Alkylation of ketones with primary alcohols driven by visible light and bimetallic gold and palladium nanoparticles supported on transition metal oxide
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- 作者：Meifen Bai ; Hui Xin ; Zhi Guo ; Dapeng Guo ; Yan Wang ; Peng Zhao ; Jingyi Li ; lijingyicn@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：α-Alkylation ; Ketones ; Primary alcohols ; Visible light ; Bimetallic photo-catalysts
- 刊名：Applied Surface Science
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：391
- 期：part_PB
- 页码：617-626
- 全文大小：2701 K
文摘
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The catalysts were prepared by reduction method at room temperature.
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α-Alkylation of ketones and primary alcohols occurred on Au-Pd/CeO2 in visible light.
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Superior catalytic activities were shown on bimetallic Au-Pd/CeO2 catalysts.
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The catalyst can be reused for 4 times.
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The mechanism of the synthesis for ketones was proposed.
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