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Dielectric nonlinearity and electric breakdown behaviors of Ba0.95Ca0.05Zr0.3Ti0.7O3 ceramics for energy storage utilizations
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Contributions to the dielectric constants under bias electric field were resolved.

The intrinsic mechanism dominated the dielectric response under strong field.

The electric breakdown of the ceramics initially occurred on the surfaces.

Oxygen vacancies were determined to be the mobile charge carriers in the ceramics.

The oxygen vacancies in the ceramics were contributive to the initial breakdown.

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