Particle size studies to reveal crystallization mechanisms of the metal organic framework HKUST-1 during sonochemical synthesis
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- 作者：Mitchell R. Armstronga ; Sethuraman Senthilnathana ; Christopher J. Balzera ; Bohan Shana ; Liang Chenb ; chenliang@nimte.ac.cn" class="auth_mail" title="E-mail the corresponding author ; Bin Mua ; bmu@asu.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Sonochemistry ; Ultrasound-assisted synthesis ; Metal organic frameworks ; CuBTC or HKUST-1 ; Crystallization ; Particle size distribution
- 刊名：Ultrasonics Sonochemistry
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：34
- 期：Complete
- 页码：365-370
- 全文大小：1158 K
文摘
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A competitive mechanism for MOF growth in sonochemical reactor is proposed.
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The mechanism includes constructive crystal growth and deconstructive sonofragmentation.
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Sonication amplitude and solvent choice are primary factors determining the particle size of HKUST-1.
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Sonicator tip size and reactor size are primary factors contributing to particle size distribution.
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Sonication time has a significant effect on yield.
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