Ultrasound irritation enhanced heterogeneous activation of peroxymonosulfate with Fe₃O₄ for degradation of azo dye

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• 作者：Jie Liu ; Jihao Zhou ; Zhaoxia Ding ; Zhiwei Zhao ; ^{zhaozhiweihit@gmail.com" class="auth_mail" title="E-mail the corresponding author} ; Xiao Xu ; Zhendong Fang ; ^{fangzhendong@hotmail.com" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Magnetite ; Ultrasound ; Peroxymonosulfate ; Azo dye ; Sulfate radicals
• 刊名：Ultrasonics Sonochemistry
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：34
• 期：Complete
• 页码：953-959
• 全文大小：1051 K

文摘

Magnetic Fe₃O₄ nanoparticles were synthesized and used as peroxymonosulfate (PMS) activator in the presence of ultrasound (US) irritation for azo dye degradation in this study. At pH 7.0 and temperature 298 K, Fe₃O₄ nanoparticles were able to activate PMS under ultrasound irritation to produce sulfate radicals for acid orange 7 (AO7) removal in 30 min. Higher catalysts dosage, neutral pH as well as optimum values of PMS dosage and ultrasound power favored the AO7 degradation. Fe₃O₄ displayed excellent stability and reusability in the US/PMS system. Both of the sulfate radicals and hydroxyl radicals were produced in the reaction and sulfate radicals were the dominant according to the scavenging tests and electron paramagnetic resonance (ESR) tests. The mechanisms of ultrasound irritation enhanced PMS activation in the presence of Fe₃O₄ were proposed based on the results and literatures.