Simulation of polyurethane/activated carbon surface interactions

详细信息    查看全文

• 作者：Tamara Travinskaya ; Andrey Perekhrest ; Yuri Savelyev ; Nick Kanellopoulos ; Kyriakos Papadopoulos ; Kali Agiamarnioti
• 关键词：Urea ; Semicarbazide ; Ethylurethane ; Polyurethane ; Activated carbon ; Surface
• 刊名：Applied Surface Science
• 出版年：2010
• 出版时间：15 April 2010
• 年：2010
• 卷：256
• 期：13
• 页码：4391-4396
• 全文大小：546 K

文摘

The influence of interfacial structure on interfacial properties between activated carbon filler and surrounding organic matrix of composites has been studied by infrared and NMR spectroscopy. Urea, semicarbazide and ethylurethane, component parts of polyurethane, have been used as organic model compounds in order to predict the interactions between the activated carbon surface and polar groups of real polyurethane molecule. It was shown that organic matrix/activated carbon interphase presented a region where the filler and matrix phases were chemically and/or physically combined. The spectra of the organic matrix undergo significant changes with increase of carbon content. Due to the surface reactive functionalities the activated carbon is considered not only as filler, influenced on the sorption properties of the composition, but also as a physicochemical modifier of the polyurethane matrix.