Catalytic steam gasification of JY coal char (ash-rich) and AF char (ash-free) is studied.
The relative catalytic activities of Li, Na and K carbonates depend on minerals in char.
Impregnating Ca(OH)2 to JY coal facilitates the gasification rate for the three alkali catalysts.
Only the binary K2CO3/Ca(OH)2 catalyst has a better activity for gasification of AF char.
There are some different catalytic synergies between Ca(OH)2 and each alkali carbonate.
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