Solubility of ZnFe2O4 can be increased by pretreatment with the CaO addition.
Zinc was leached from as-supplied EAF dust and CaO treated dust by using NH4Cl.
All of zinc in CaO treated dust was successfully leached in the NH4Cl solution.
While about 20% of calcium was leached, no iron was leached in the NH4Cl solution.
The leached Ca2Fe2O5 residue can be supplied to the steelmaking industry.
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