A nanohybrid of platinum nanoparticles-porous ZnO spheres-hemin was synthesized.
Hemin was adsorbed onto Pt–pZnO by ester-like binding between hemin and ZnO.
Alkaline phosphatase catalyzed 1-naphthyl phosphate and in situ produce electroactive substance 1-naphthol.
Pt–pZnO–hemin exhibited electrocatalytic activity toward 1-naphthol.
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