A nonenzymatic electrochemical immunosensor based on the Ag@MSN nanoparticles was developed for the detection of MC-LR.
Ag@MSN nanoparticle which possessed an intrinsic enzyme catalytic activity similar to that of horseradish peroxidase was used to replace protein enzyme to improve the stability and sensitivity.
The method is highly sensitive with the detection limit of 0. 2 ng/mL.
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