Efficient solar-thermal conversion by semiconducting β-FeSi2 at high temperature. The high efficiency originates from a steep cut-off at the band-edge absorption. Optical constants of β-FeSi2 nanoparticles+SiO2 composites are controllable. Thermally stable silicides in SiO2 matrices suitable for high-temperature operation. Diffusion of Si from silicides to low-emissivity metals should be prevented.