Hydrogenation of methyl methacrylate under mild conditions using biosynthesis Ru catalyst

详细信息    查看全文

• 作者：Hongling Zhou ; Yangqiang Huang ; Youwei Cheng ; ^{ywcheng@zju.edu.cn} ; ^uway@163.com ; Lijun Wang ; Xi Li
• 关键词：Methyl methacrylate ; Hydrogenation ; Ru-based catalyst ; Bio-reduction
• 刊名：Journal of Industrial and Engineering Chemistry
• 出版年：2017
• 出版时间：25 March 2017
• 年：2017
• 卷：47
• 期：Complete
• 页码：221-227
• 全文大小：1530 K
• 卷排序：47

文摘

Hydrogenation of methyl methacrylate (MMA) was investigated over Ru-based catalyst supported on active carbons (AC), which was prepared by bio-reduction method, using C. Platycladi (CP) leaf extract as reductant. By varying reaction temperature, hydrogen pressure and reaction time, hydrogenation of MMA over the biosynthesis Ru-based catalyst was carried out, and resulted the optimum conditions, 30 °C (room temperature), 2.0 MPa, and 50 min. The as-prepared Ru/AC catalyst showed high catalytic activity towards the hydrogenation of MMA, affording 100% of MMA conversion even under mild conditions without solvent and methyl isobutyrate was the only product.