Synthesis, structure, lattice energy and enthalpy of 2D hybrid perovskite [NH₃(CH₂)₄NH₃]CoCl_4, compared to [NH₃(CH₂)_nNH₃]CoCl₄, n=3-9

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• 作者：Seham K. Abdel-Aal ; ^{seham@sci.cu.edu.eg} ; Ahmed S. Abdel-Rahman
• 关键词：A1. Crystal structure ; A2. Growth from high temperature solutions ; A2. Single crystal growth ; A3. Quantum wells ; B1. Perovskites ; B1. Inorganic compound
• 刊名：Journal of Crystal Growth
• 出版年：2017
• 出版时间：1 January 2017
• 年：2017
• 卷：457
• 期：Complete
• 页码：282-288
• 全文大小：1221 K
• 卷排序：457

文摘

[NH3(CH2)4NH3]CoCl4 related to the 2D perovskite hybrids of the formula A2MX4. Complete structure data of [NH3(CH2)4NH3]CoCl4 is provided. The structure form infinite layers of (organic/inorganic) connected by H- bond. Layered structure of hybrids resemble to self organized multiple quantum wells. Lattice energy and enthalpy are decrease as organic chain length increase.