Functionalization of the naturally occurring linalool and nerol by the palladium catalyzed oxidation of their trisubstituted olefinic bonds

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• 作者：Luciana A. Parreira^a ; ^b ; Ana F. Azevedo^c ; Luciano Menini^c ; Elena V. Gusevskaya^a ; ^{elena@ufmg.br}
• 关键词：Bio-renewables ; Linalool ; Nerol ; Oxidation ; Oxygen ; Palladium
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：429-434
• 全文大小：503 K
• 卷排序：426

文摘

Linalool and nerol are bio-renewable substrates found in many essential oils. Pd(OAc)2/p-benzoquinone system catalyses the aerobic oxidation of linalool and nerol. No requirement in auxiliary electron-transfer mediators under 5–10 atm of oxygen. Sterically encumbered internal acyclic olefinic bonds are involved in the oxidation. Fragrant poly-functionalized monoterpenoid compounds are obtained in good yields.