Enthalpies of solution and enthalpies of solvation of organic solutes in ethylene glycol at 298.15 K: Prediction and analysis of intermolecular interaction contributions

详细信息    查看全文

• 作者：Mikhail A. Stolov^a ; Ksenia V. Zaitseva^a ; Mikhail A. Varfolomeev^a ; ^{vma.ksu@gmail.com} ; ^{mikhail.varfolomeev@kpfu.ru} ; William E. Acree^b
• 关键词：Ethylene glycol ; Solution calorimetry ; Enthalpy of solution ; Enthalpy of solvation ; Multi-parameter correlation ; Hydrogen bond
• 刊名：Thermochimica Acta
• 出版年：2017
• 出版时间：10 February 2017
• 年：2017
• 卷：648
• 期：Complete
• 页码：91-99
• 全文大小：745 K
• 卷排序：648

文摘

Enthalpies of solution were measured for 28 solutes dissolved in ethylene glycol. Enthalpies of solvation were calculated for 68 solutes dissolved in ethylene glycol. Equations were derived for predicting enthalpies of solvation in ethylene glycol. Enthalpies of specific interactions of solutes in ethylene glycol were determined. Enthalpies of specific interactions in ethylene glycol and methanol are equal.