Nano-grains can be formed in AZ31B by two-sided simultaneous laser shock peening. LSP induces symmetric compressive residual stress on both sides of 4 mm thick AZ31B. Corrosion potential of LSP sample increased 131 mV compared to original sample. Corrosion current density of LSP sample reduced by 85.4% compared to original sample. SCC susceptibility index of LSP sample reduced by 47.5% compared to original sample.