Influence of Al³⁺/P⁵⁺ ions substitution on the structure and luminescence properties of Sr₂SiO₄:Eu²⁺ phosphors for white light emitting diodes

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• 作者：Yulong Wang^a ; ^b ; Wentao Zhang^a ; ^c ; ^{zhangwentao2005@163.com} ; Xianfei Chen^a ; Haiying Du^a ; Junfeng Li^a ; Kehui Qiu^a
• 关键词：Sr2SiO4 phosphor ; Solid-state reaction ; Partial substitution ; Luminescence ; White LEDs
• 刊名：Ceramics International
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：43
• 期：2
• 页码：2824-2828
• 全文大小：661 K
• 卷排序：43

文摘

Sr2Si1-xAlxO4:Eu2+ and Sr2Si1-yPyO4:Eu2+ with Al3+/P5+ ions partial substitution were prepared using a solid-state reaction method. The effects of Al3+/P5+ substitution on both structure and luminescence properties of Sr2SiO4:Eu2+ was investigated. A standard Sr2SiO4 structure was observed in the X-ray diffraction spectra of the Sr2Si1-xAlxO4:Eu2+ and Sr2Si1-yPyO4:Eu2+ samples. Some diffraction peaks, however, were changed after Al3+/P5+ ions substitution due to the different ion radius. Upon excitation with 367 nm wavelength, all phosphor samples exhibit a broad emission band ranging from 420 nm to 680 nm, which is attributed to the 4f65d1→4f7 transition of the Eu2+ ions. The luminescence intensity of Sr2Si0.92Al0.08O4:Eu2+ and Sr2Si0.94P0.06O4:Eu2+ is 1.55 and 1.38 times higher, respectively, than that of Sr2SiO4:Eu2+. In addition, the luminescence lifetime of the Sr2SiO4:Eu2+ was also prolonged significantly by the introduction of Al3+ and P5+ ions. Overall, the results indicated that the application of Sr2SiO4:Eu2+ phosphors was effectively enhanced by Al3+/P5+ partial substitution in white light emitting diodes.