Successive RAFT polymerization of poly(ethylene oxide) methyl ether methacrylates with different length of PEO chains giving diblock brush copolymers

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• 作者：Vaidas Klimkevicius ; ^{vaidas.klimkevicius@gmail.com} ; Ricardas Makuska
• 关键词：RAFT polymerization ; Diblock copolymers ; Brush copolymers ; PEO methacrylate ; One-pot polymerization
• 刊名：European Polymer Journal
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：86
• 期：Complete
• 页码：94-105
• 全文大小：1338 K
• 卷排序：86

文摘

RAFT polymerization of PEO methacrylate macromonomers is well controllable. Chains of diblock brush copolymers remain “living”. Chain extension of brush polymers gives diblock copolymers with higher dispersity. “One pot” RAFT polymerization is preferential to get diblock brush copolymers.