Geometrical effects during crystallization under confinement in electrospun core-shell fibers. DSC study of crystallization kinetics

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• 作者：Arkadiusz Gradys ; ^{argrad@ippt.pan.pl}
• 关键词：Core-shell fibers ; Confinement effects ; Crystallization kinetics ; DSC ; Polyethylene glycol
• 刊名：Polymer
• 出版年：2017
• 出版时间：13 January 2017
• 年：2017
• 卷：108
• 期：Complete
• 页码：383-394
• 全文大小：2835 K
• 卷排序：108

文摘

Core-shell fibers obtained by coaxial electrospinning as system of quasi one-dimensional geometry. Description of geometrical effects of non-trivial crystallization behavior with Avrami model and the Turnbull and Fisher nucleation theory. Size effect on the crystallization kinetics and thermodynamic parameters.