Relationship between the Skew Angle and Interplanar Distance in Four Bis(phthalocyaninato)lanthanide(III) Tetrabutylammonium Salts ([NBun4][LnIIIPc2]

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• 作者：Naoto Koike ; Hidehiro Uekusa ; Yuji Ohashi ; Chokto Harnoode ; Fusao Kitamura ; Takeo Ohsaka ; and Koichi Tokuda
• 刊名：Inorganic Chemistry
• 出版年：1996
• 出版时间：September 25, 1996
• 年：1996
• 卷：35
• 期：20
• 页码：5798 - 5804
• 全文大小：228K
• 年卷期：v.35,no.20(September 25, 1996)
• ISSN：1520-510X

文摘

Four crystal structures of the title complexes havebeen analyzed by X-ray crystallography. 1:C₈₀H₆₈N₁₇Nd,a= 17.0545(6) Å, c = 22.807(3) Å, tetragonal,P4/ncc, Z = 4. 2:C₈₀H₆₈N₁₇Gd, a =17.399(8) Å, c = 11.377(6)Å, tetragonal, P42₁2, Z = 2.3:C₈₀H₇₀N₁₇OHo, a =18.096(5) Å, c = 11.079(6) Å, tetragonal,P42₁2, Z = 4.4:C₈₀H₇₀N₁₇OLu, a =18.171(3) Å, c = 10.987(4) Å, tetragonal,P4/nmm, Z = 2. The[Ln^IIIPc₂]^- and[NBuⁿ₄]⁺ions in each crystal stack alternately in a column along the 4-foldaxis. The Ln(III) cation of each[Ln^IIIPc₂]^-iseight-coordinated by two phthalocyanato dianions (Pc). Theinterplanar distances between the two Pc rings havea linear relationship to the ionic radii of the central Ln(III)cations. The skew angles between the two Pc ringsare 6.2, 34.4, 43.2, and 45.0 for the Nd, Gd, Ho, and Lu complexes,respectively. The skew angle seems todepend on the strength of the - interaction between the two Pcrings.