Anionic Oxidative Polymerization: The Synthesis of Poly(phenylenedicyanovinylene) (PPCN2V)

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• 作者：Ryan M. Moslin ; Trisha L. Andrew ; Steven E. Kooi ; Timothy M. Swager
• 刊名：Journal of the American Chemical Society
• 出版年：2009
• 出版时间：January 14, 2009
• 年：2009
• 卷：131
• 期：1
• 页码：20-21
• 全文大小：150K
• 年卷期：v.131,no.1(January 14, 2009)
• ISSN：1520-5126

文摘

A new polymerization technique that allows for the first-ever synthesis of poly(phenylenedicyanovinylene)s (PPCN2Vs) is described. PPCN2Vs, with their high electron affinities and structural versatility, seem ideally suited to address the need for new n-type polymers. Remarkably the polymers presented herein become more photoluminescent, in the thin film, under continuous irradiation.