{Zn6[MeN(CH2CO2)(CH2PO3)]6(Zn)}4- Anion: The First Example of the Oxo-Bridged Zn6 Octahedron with a C

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• 作者：Chong Lei ; Jiang-Gao Mao ; Yan-Qiong Sun ; Hui-Yi Zeng ; and Abraham Clearfield
• 刊名：Inorganic Chemistry
• 出版年：2003
• 出版时间：October 6, 2003
• 年：2003
• 卷：42
• 期：20
• 页码：6157 - 6159
• 全文大小：170K
• 年卷期：v.42,no.20(October 6, 2003)
• ISSN：1520-510X

文摘

Hydrothermal reactions of N-(phosphonomethyl)-N-methylglycine,MeN(CH₂CO₂H)(CH₂PO₃H₂) (H₃L), with zinc(II) acetate resulted inthe formation of a novel zinc carboxylate-phosphonate, {Zn₆L₆(Zn)}{Zn(H₂O)₆}₂·22H₂O (1). The structure of 1 contains aheptanuclear zinc phosphonate cluster anion, {Zn₆L₆(Zn)}^4-, inwhich seven zinc(II) cations form an unusual Zn₆(Zn) centeredoctahedron with six of its Zn₃ triangle faces each further cappedby a phosphonate group. The Zn(II) cations of the Zn₆ octahedronare five-coordinated whereas the centered Zn(II) cation is octahedrally coordinated. Packing of these cluster anions createsmicropores occupied by the hydrated zinc(II) cations as well aslattice water molecules. The structural skeleton of 1 is retainedafter the removal of the lattice water molecules.