Structural Characterization and Luminescence Behavior of a Silver(I) 1D Polymeric Chain Constructed via a Bridge with Unusual 4,5-Diazospirobifluorene and Perchlorate

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• 作者：Chih-Chieh Wang ; Cheng-Han Yang ; Shih-Min Tseng ; Sue-Yi Lin ; Ti-Yu Wu ; Ming-Ren Fuh ; Gene-Hsiang Lee ; Ken-Tsung Wong ; Ruei-Tang Chen ; Yi-Ming Cheng ; and Pi-Tai Chou
• 刊名：Inorganic Chemistry
• 出版年：2004
• 出版时间：August 9, 2004
• 年：2004
• 卷：43
• 期：16
• 页码：4781 - 4783
• 全文大小：185K
• 年卷期：v.43,no.16(August 9, 2004)
• ISSN：1520-510X

文摘

A new polymeric silver complex, [Ag₂(L₂)(ClO₄)₂] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibitinteresting luminescence properties in a single crystal. Structuralanalysis reveals a one-dimensional chain, which contains a [Ag₂(L₂)]²⁺ dimer bridged with ClO₄^-. The Ag···Ag distances are 2.776(1) and 4.575(1) Å incorporated by two L ligands and by a ClO₄^-bridge, respectively.