Cleavage of Hydrazine N-N Bonds by RuMo3S4 Cubane-Type Clusters
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- 作者：Izuru Takei ; Keita Dohki ; Koji Kobayashi ; Toshiaki Suzuki ; and Masanobu Hidai
- 刊名：Inorganic Chemistry
- 出版年：2005
- 出版时间：May 30, 2005
- 年：2005
- 卷：44
- 期：11
- 页码：3768 - 3770
- 全文大小：75K
- 年卷期：v.44,no.11(May 30, 2005)
- ISSN：1520-510X
文摘
The mixed-metal cubane-type clusters [(Cp*Mo)3(
3-S)4RuH2(PR3)][PF6] [Cp* = 
5-C5Me5; R = Ph (2), Cy (5)] were effective for theN-N bond cleavage of hydrazine and phenylhydrazine via adisproportionation reaction. The ammonia cluster [(Cp*Mo)3(3-S)4Ru(NH3)(PPh3)][PF6] (3) and/or the unprecedented double-cubane-type cluster with bridging nitrogenous ligands [{(Cp*Mo)3(3-S)4Ru}2(2-NH2)(2-NHNH2)][PF6]2 (4) were isolated from thereaction mixtures, and their structures were determined by X-raydiffraction studies.
3-S)4RuH2(PR3)][PF6] [Cp* = 5-C5Me5; R = Ph (2), Cy (5)] were effective for theN-N bond cleavage of hydrazine and phenylhydrazine via adisproportionation reaction. The ammonia cluster [(Cp*Mo)3(3-S)4Ru(NH3)(PPh3)][PF6] (3) and/or the unprecedented double-cubane-type cluster with bridging nitrogenous ligands [{(Cp*Mo)3(3-S)4Ru}2(2-NH2)(2-NHNH2)][PF6]2 (4) were isolated from thereaction mixtures, and their structures were determined by X-raydiffraction studies.© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |