Radiation Effect on the Thermal Cracking of n-Hexadecane. 2. A Kinetic Approach to Chain Reaction

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• 作者：Guozhong Wu ; Yosuke Katsumura ; Chihiro Matsuura ; Kenichi Ishigure ; and Junichi Kubo
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：1997
• 出版时间：September 1997
• 年：1997
• 卷：36
• 期：9
• 页码：3498 - 3504
• 全文大小：213K
• 年卷期：v.36,no.9(September 1997)
• ISSN：1520-5045

文摘

Rate equations of n-hexadecane decomposition underdifferent conditions were derived on thebasis of a simplified radical reaction scheme. Assuming theinitiation rate for radiation istemperature-independent, Arrhenius parameters of some importantreactions involving n-hexadecane cracking have been estimated by a series of kinetictreatments. Our estimated valuesare shown to be in good agreement with those reported in theliterature.