Ultralarge and Thermally Stable Electro-Optic Activities from Supramolecular Self-Assembled Molecular Glasses

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• 作者：Tae-Dong Kim ; Jae-Wook Kang ; Jingdong Luo ; Sei-Hum Jang ; Jae-Won Ka ; Neil Tucker ; Jason B. Benedict ; Larry R. Dalton ; Tomoko Gray ; René ; M. Overney ; Dong Hun Park ; Warren N. Herman ; Alex K.-Y. Je
• 刊名：Journal of the American Chemical Society
• 出版年：2007
• 出版时间：January 24, 2007
• 年：2007
• 卷：129
• 期：3
• 页码：488 - 489
• 全文大小：87K
• 年卷期：v.129,no.3(January 24, 2007)
• ISSN：1520-5126

文摘

A series of molecular engineered organic glasses have been prepared to exploit the use of complementary Ar-Ar^F interactions to improve poling efficiency. These self-organized molecular glasses have also been used as host in the binary chromophore system to further improve the number density of chromophores and r₃₃ values. Ultrahigh r₃₃ values (up to 327 pm/V at the wavelength of 1310 nm) and good temporal stability could be achieved in these materials.