Palladium-Catalyzed Regio- and Enantioselective Allylic Alkylation of Bis Allylic Carbonates Derived from Morita-Baylis-Hillman Adducts

详细信息    查看全文

• 作者：Barry M. Trost ; Megan K. Brennan
• 刊名：Organic Letters
• 出版年：2007
• 出版时间：September 27, 2007
• 年：2007
• 卷：9
• 期：20
• 页码：3961 - 3964
• 全文大小：139K
• 年卷期：v.9,no.20(September 27, 2007)
• ISSN：1523-7052

文摘

Morita-Baylis-Hillman diene adducts are used as substrates in the palladium-catalyzed asymmetric allylic alkylation reaction with oxygen andcarbon nucleophiles in good regio- and enantioselectivity.