Facile Route to Nitrides: Transformation from Single Element to Binary and Ternary Nitrides at Moderate Temperature through a New Modified Solid-State Metathesis

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• 作者：Bo Song ; Xiaolong Chen ; Jiecai Han ; Jikang Jian ; Wanyan Wang ; Hongbo Zuo ; Xinghong Zhang ; Songhe Meng
• 刊名：Inorganic Chemistry
• 出版年：2009
• 出版时间：November 16, 2009
• 年：2009
• 卷：48
• 期：22
• 页码：10519-10527
• 全文大小：1252K
• 年卷期：v.48,no.22(November 16, 2009)
• ISSN：1520-510X

文摘

In this article, we report a new modified solid-state metathesis pathway to synthesize nitrides using Li₃N as a nitrification reagent to transform single element to nitrides. In this process, not only binary (including mono- and multinitrides) but also ternary nitrides can be approached by varying the molar ratio of Li₃N to a single element. A possible two-step reaction mechanism for Li₃N and single elements was proposed. This study provides a promising route to meet the increasing demand in energy savings and environmental protection for materials synthesis.