The synthesis of multiwalled
carbon nanotubes (MWCNTs) and
carbon
balls (CBs)
catalyzed by ferro
cene (F
c), Mo(CO)
5L (L = CO,
tBuNC), and bimetalli
c catalyst systems(F
c/M(CO)
5tBuNC; M = W or Mo) was investigated. These rea
ctions were
carried out inflowing 5% H
2 in Ar in the temperature range 700-900
C. Under the rea
ction
conditions,F
c yielded CNTs and CBs, while the M(CO)
5L
complexes yielded little
carbona
ceous material.Depending on the temperature and weight ratio of the metals used, mixtures of F
c andM(CO)
5L generated varying amounts of CNTs and CBs. EDS and TEM analysis revealedthe formation of large parti
cles of Mo/Fe alloys. It was observed that the diameters of theCNTs
catalyzed by F
c are smaller while the diameters of CBs are larger relative to thediameters of CNTs and CBs produ
ced by the bimetalli
c catalyst systems. In all instan
cesMWCNTs were produ
ced, whi
ch
contrasts with the single-walled CNTs produ
ced by Fe/Mo-supported heterogeneous
catalyst systems.