A Symmetric Derivative of the Trimetallic Nitride Endohedral Metallofullerene, Sc3N@C80

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• 作者：Erick B. Iezzi ; James C. Duchamp ; Kim Harich ; Tom E. Glass ; Hon Man Lee ; Marilyn M. Olmstead ; Alan L. Balch ; and Harry C. Dorn
• 刊名：Journal of the American Chemical Society
• 出版年：2002
• 出版时间：January 30, 2002
• 年：2002
• 卷：124
• 期：4
• 页码：524 - 525
• 全文大小：75K
• 年卷期：v.124,no.4(January 30, 2002)
• ISSN：1520-5126

文摘

The reaction of Sc₃N@C₈₀ with 6,7-dimethoxyisochroman-3-one (¹³C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single ¹³C labeled monoadduct product that was purified by HPLC. The ¹³C labeled monoadduct was characterized by ¹H NMR, ¹³C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc₃N@C₈₀ cage.