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Ultrasensitive NH3 Gas Sensor from Polyaniline Nanograin Enchased TiO2 Fibers
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  • 作者:Jian Gong ; Yinhua Li ; Zeshan Hu ; Zhengzhi Zhou ; Yulin Deng
  • 刊名:Journal of Physical Chemistry C
  • 出版年:2010
  • 出版时间:June 3, 2010
  • 年:2010
  • 卷:114
  • 期:21
  • 页码:9970-9974
  • 全文大小:228K
  • 年卷期:v.114,no.21(June 3, 2010)
  • ISSN:1932-7455
文摘
In this communication, we reported for the first time an ultrasensitive nanostructrued sensor that can detect 50 ppt of NH3 gas in air. Specifically, nanograins of a p-type conductive polymer, polyaniline (PANI), are enchased on an electrospun n-type semiconductive TiO2 fiber surface. The resistance of the p−n heterojunctions combining with the bulk resistance of PANI nanograins can function as electric current switches when NH3 gas is absorbed by PANI nanoparticles. As a result, the sensor sensitivity can be significantly improved. The sensor fabricated in this work is 1000 times more sensitive than the best PANI sensor reported in the literature.

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