Mobilizing Cu(I) for Carbon鈭扖arbon Bond Forming Catalysis in the Presence of Thiolate. Chemical Mimicking of Metallothioneins

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• 作者：Zhihui Zhang ; Matthew G. Lindale ; Lanny S. Liebeskind
• 刊名：Journal of the American Chemical Society
• 出版年：2011
• 出版时间：April 27, 2011
• 年：2011
• 卷：133
• 期：16
• 页码：6403-6410
• 全文大小：947K
• 年卷期：v.133,no.16(April 27, 2011)
• ISSN：1520-5126

文摘

Copper(I) is rendered catalytically viable in the presence of thiolate by the design of a small molecule chemical analogue of the metallothionein system in which an N鈭扥 reactant serves the same conceptual purpose of the S鈭扴 reactant of the biological system.