Pd-Catalyzed Asymmetric Allylic Etherizations with Oximes by Chiral Alkene-Phosphine Ligands

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• 作者：Ziping Cao ; Zhaoqun Liu ; Yilin Liu ; Haifeng Du
• 刊名：Journal of Organic Chemistry
• 出版年：2011
• 出版时间：August 5, 2011
• 年：2011
• 卷：76
• 期：15
• 页码：6401-6406
• 全文大小：864K
• 年卷期：v.76,no.15(August 5, 2011)
• ISSN：1520-6904

文摘

Palladium-catalyzed asymmetric allylic etherizations with a variety of oximes as nucleophiles utilizing a chiral alkene-phosphine hybrid ligand have been successfully achieved for the first time to afford the optical active oxime ethers in high yields with good to excellent enantioselectivities.