Synthesis of N-Confused Porphyrin Derivatives with a Substituted 3-C Position

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• 作者：Xiaofang Li ; Bin Liu ; Pinggui Yi ; Rongqiong Yi ; Xianyong Yu ; Piotr J. Chmielewski
• 刊名：Journal of Organic Chemistry
• 出版年：2011
• 出版时间：April 1, 2011
• 年：2011
• 卷：76
• 期：7
• 页码：2345-2349
• 全文大小：819K
• 年卷期：v.76,no.7(April 1, 2011)
• ISSN：1520-6904

文摘

Active methylene compounds such as 5,5-dimethylcyclohexane-1,3-dione, cyclohexane-1,3-dione, 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one, 1,3-dimethyl-1H-pyrazol-5(4H)-one, and 3-methylisoxazol-5(4H)-one react with the 3-C position of N-confused porphyrin in THF for 5 min to afford a novel type of N-confused porphyrin derivatives in good yield without the need of any catalyst.