Isolation and Reactivity of 1,4,2-Diazaborole

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• 作者：Bochao Su ; Yongxin Li ; Rakesh Ganguly ; Jenny Lim ; Rei Kinjo
• 刊名：Journal of the American Chemical Society
• 出版年：2015
• 出版时间：September 9, 2015
• 年：2015
• 卷：137
• 期：35
• 页码：11274-11277
• 全文大小：384K
• ISSN：1520-5126

文摘

An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6蟺-electrons over the BC₂N₂ five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.