Enantioselective Adsorption of Chiral Amines on an Induced Helical Poly(bis(4-carboxyphenoxy)phosphazene): Chiral Filter Effect

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• 作者：Katsuhiro Maeda ; Kenji Kuroyanagi ; Shin-ichiro Sakurai ; Toshio Yamanaka ; Eiji Yashima
• 刊名：Macromolecules
• 出版年：2011
• 出版时间：April 26, 2011
• 年：2011
• 卷：44
• 期：8
• 页码：2457-2464
• 全文大小：919K
• 年卷期：v.44,no.8(April 26, 2011)
• ISSN：1520-5835

文摘

Optically inactive poly((bis(4-carboxyphenoxy)phosphazene) (poly-1) showed a large optical rotation upon complexation with optically active (R)- or (S)-1-phenylethylamine (2) in DMSO after annealing the complex solution at 65 掳C for ca. 2 h and maintained its optical activity in the presence of an equimolar amount of the opposite-handed 2. The detailed analysis of the enantiomeric excess of 2 adsorbed on the poly-1 revealed that the helical poly-1 induced by (R)- or (S)-2 most likely acts as a 鈥?i>chiral filter鈥?to exclude one enantiomer from racemic 2, resulting in the retention of its induced helical structure.