Highly Stereoselective Facile Synthesis of 2-Acetoxy-1,3(E)-alkadienes via a Rh(I)-Catalyzed Isomerization of 2,3-Allenyl Carboxylates

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• 作者：Xiaobing Zhang ; Chunling Fu ; Shengming Ma
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：April 15, 2011
• 年：2011
• 卷：13
• 期：8
• 页码：1920-1923
• 全文大小：788K
• 年卷期：v.13,no.8(April 15, 2011)
• ISSN：1523-7052

文摘

A highly stereoselective Rh(I)-catalyzed 1,3-acetoxyl rearrangement of 1,2-allen-3-yl carboxylates leading to 2-acetoxy-1,3(E)-alkadienes has been developed. In addition to the high catalytic efficiency and the scope, the excellent E-selectivity of the double bond is remarkable.