Combinational Synthetic Approaches for Isoreticular and Polymorphic Metal鈥揙rganic Frameworks with Tuned Pore Geometries and Surface Properties

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• 作者：Seok Jeong ; Dongwook Kim ; Sunyoung Shin ; Dohyun Moon ; Sung June Cho ; Myoung Soo Lah
• 刊名：Chemistry of Materials
• 出版年：2014
• 出版时间：February 25, 2014
• 年：2014
• 卷：26
• 期：4
• 页码：1711-1719
• 全文大小：617K
• 年卷期：v.26,no.4(February 25, 2014)
• ISSN：1520-5002

文摘

Isoreticular and polymorphic 3-D MOFs were prepared via the combination of direct solvothermal reactions, postsynthetic ligand exchanges of the MOFs prepared via the direct solvothermal reactions, and postsynthetic ligand insertions into a 2-D MOF. The appropriate pore dimensions, surface areas, and adsorption enthalpies of the MOFs combined well to produce the largest working CO₂ capture capacities via the pressure swing adsorption process.