Synthesis and Characterization of Cyclooctatetrathiophenes with Different Connection Sequences

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• 作者：Yong Wang ; Jinsheng Song ; Li Xu ; Yuhe Kan ; Jianwu Shi ; Hua Wang
• 刊名：Journal of Organic Chemistry
• 出版年：2014
• 出版时间：March 7, 2014
• 年：2014
• 卷：79
• 期：5
• 页码：2255-2262
• 全文大小：439K
• 年卷期：v.79,no.5(March 7, 2014)
• ISSN：1520-6904

文摘

Based on the selectivity of deprotonation of 5,5鈥?bistrimethylsilyl-2,3鈥?bithiophene (4) in the presence of n-BuLi, three new cyclooctatetrathiophenes (COThs), COTh-1, COTh-2, and COTh-3 have been efficiently developed via intermolecular or intramolecular cyclizations. Their crystal structures clearly show that the different connectivity sequence of the thiophene rings in the molecules. The CV data and UV鈥搗is absorbance spectra of COThs are also described. In addition, the time-dependent density functional theory (TDDFT) calculations accurately reproduce experimental observations and afford band assignment.