Copper-Mediated Trifluoromethylthiolation of 伪-Diazoesters

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• 作者：Mingyou Hu ; Jian Rong ; Wenjun Miao ; Chuanfa Ni ; Yongxin Han ; Jinbo Hu
• 刊名：Organic Letters
• 出版年：2014
• 出版时间：April 4, 2014
• 年：2014
• 卷：16
• 期：7
• 页码：2030-2033
• 全文大小：289K
• 年卷期：v.16,no.7(April 4, 2014)
• ISSN：1523-7052

文摘

A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient 伪-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.