Self-Healing of Core鈥揝hell Magnetic Polystyrene Nanocomposites

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• 作者：Mitra Yoonessi ; Bradley A. Lerch ; John A. Peck ; Richard B. Rogers ; Francisco J. Sol谩-Lopez ; Michael A. Meador
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2015
• 出版时间：August 12, 2015
• 年：2015
• 卷：7
• 期：31
• 页码：16932-16937
• 全文大小：314K
• ISSN：1944-8252

文摘

High heat generation is reported in core鈥搒hell magnetic nanoparticle polystyrene (PS) nanocomposites (3.5, 10 wt %) when they are placed in a high-frequency ac magnetic field. These magnetic nanoparticles with cobalt iron oxide core and manganese iron oxide shell were synthesized and characterized by wide-angle X-ray scattering (WAX), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and ac field gradient magnetometery. When placed in a high-frequency ac magnetic field, the thermal energy generated in the magnetic polystyrene nanocomposites resulted in a surface temperature increase. The heat generation is attributed to the contribution of N茅el relaxation and hysteresis of the core鈥搒hell magnetic nanoparticles in the solid state. The maximum surface temperature increased with increasing nanoparticle content and resulted in melting of the magnetic polystyrene nanocomposite.