Copper(II) Acetate-Catalyzed Addition of Arylboronic Acids to Aromatic Aldehydes

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• 作者：Hanmei Zheng ; Qiang Zhang ; Jiuxi Chen ; Miaochang Liu ; Shuanghua Cheng ; Jinchang Ding ; Huayue Wu ; Weike Su
• 刊名：Journal of Organic Chemistry
• 出版年：2009
• 出版时间：January 16, 2009
• 年：2009
• 卷：74
• 期：2
• 页码：943-945
• 全文大小：152K
• 年卷期：v.74,no.2(January 16, 2009)
• ISSN：1520-6904

文摘

A novel copper-catalyzed protocol for the synthesis of carbinol derivatives has been developed. In the presence of copper(II) acetate and dppf, carbinol derivatives were prepared by the addition of arylboronic acids to aromatic aldehydes in good to excellent yields. Moreover, the rigorous exclusion of air or moisture is not required in these transformations.