Metal−Organic Framework with Rationally Tuned Micropores for Selective Adsorption of Water over Methanol

详细信息    查看全文

• 作者：Banglin Chen ; Yanyan Ji ; Ming Xue ; Frank R. Fronczek ; Eric J. Hurtado ; Jalal U. Mondal ; Chengdu Liang ; Sheng Dai
• 刊名：Inorganic Chemistry
• 出版年：2008
• 出版时间：July 7, 2008
• 年：2008
• 卷：47
• 期：13
• 页码：5543 - 5545
• 全文大小：1067K
• 年卷期：v.47,no.13(July 7, 2008)
• ISSN：1520-510X

文摘

A microporous metal−organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy)_0.5·0.55H₂O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 × 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water−methanol (1:1) liquid mixture.