Adventures in Crystal Growth: Synthesis and Characterization of Single Crystals of Complex Intermetallic Compounds

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• 作者：W. Adam Phelan ; Melissa C. Menard ; Michael J. Kangas ; Gregory T. McCandless ; Brenton L. Drake ; Julia Y. Chan
• 刊名：Chemistry of Materials
• 出版年：2012
• 出版时间：February 14, 2012
• 年：2012
• 卷：24
• 期：3
• 页码：409-420
• 全文大小：529K
• 年卷期：v.24,no.3(February 14, 2012)
• ISSN：1520-5002

文摘

The central motivation of this manuscript is to highlight the discovery of novel, highly correlated electron systems. Ternary phases with unusual ground states composed of lanthanides, transition metals, and main group elements exhibit competing behavior leading to potentially novel physical properties. These systems are known to exhibit exotic properties such as unconventional superconductivity, heavy fermion behavior, and unusual forms of magnetism. The flux-growth method provides an avenue to discover and grow large single crystalline materials so that structure鈥損hysical property relationships may be determined. The growth of high quality single crystals is necessary to elucidate the intrinsic magnetic, electronic, and thermodynamic properties and has played a significant role in advancing basic and applied materials research. In this manuscript, we review the crystal structures, physical properties, and structure鈥損roperty correlations of a select group of intermetallic compounds to demonstrate the potential for growth and discovery of materials using main group flux.

Keywords:

intermetallics; crystal growth; gallides; alumnides; antimonides; highly correlated systems; magnetism,Yb₃Pd₂Ga₈